Why does Voltorb look like a Pokeball? - Quora

Answer (1 of 2): Looking at things from an in-universe perspective, it’s strongly implied that Voltorb is an artificial lifeform that had been inadvertently created during the manufacturing of the first Poké Balls. Multiple Pokédex entries point out the fact that the Voltorb had only been discove

Voltorb, Legends of the Multi Universe Wiki

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